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Which Is More 1 Litre Or 100 Ml? What is bigger 100ml or 100 liter? 100 liter is 1000 times bigger than 100ml. Which is more 1 liter or 1 mL? Capacity is often measured using the metric units of liter (L) and milliliter (mL). Note that milliliter also uses the metric prefix of “milli-”